The CW has release two brand-new Supernatural season five premiere spots as well as eight brand new photos from the upcoming Sympathy for the Devil episode, which airs September 10th. To check out the latest TV ads and pics, follow the links below.

Picking up where the finale left off, Dean (Jensen Ackles) and Sam (Jared Padalecki) watch as the Devil (guest star Mark Pellegrino, "Lost") emerges from Hell. The brothers and Bobby (Jim Beaver) deal with the aftermath of Lucifer rising and the stunning news from Chuck the Prophet (guest star Rob Benedict) that Castiel (Misha Collins) was blown to bits by the archangels. Robert Singer directed the episode written by Eric Kripke.

Supernatural returns for its fifth season on September 10th, 2009, with Sympathy for the Devil. Jared Padalecki and Jensen Ackles are set to return as Sam and Dean Winchester. Other cast members include Jim Beaver as Bobby Singer, Misha Collins as Castiel, and Mark Pellegrino as Lucifer. This is one season premiere you won't want to miss, and it's only on the CW!