We have a brand new exclusive clip from this week's The Starter Wife episode, entitlted Das Booty Call, which airs on Friday, October 31 at 10 PM on the USA Network. Click below for a unique love scene between Debra Messing and Hart Bochner that goes awry.

Casually dating Zach forces Molly to question if he can provide her with what she wants out of a relationship.